The Photon Hypernova booster set contains 100 new cards: 50 Commons 26 Super Rares 14 Ultra Rare 10 Secret Rares
The total number of MTG cards depends on what Magic: The Gathering card count you want to use there are around 27,000 unique cards, but many more if you start to include reprints, variants, and out of game cards like art cards and tokens
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The deck boxes from the Build and Battle also make for great deck boxes to use at tournaments in your local area, bringing some flavor from your favorite sets along with you as you compete