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While you have a ritual spell in your graveyard, Black Chaos is unaffected by your opponent's activated effects

Shadowless Base Set is an early 1999 Wizards of the Coast print run, identified by the missing drop shadow along the right edge of the card art box

If youre still confused, there is a very long post over on the /r/DuelLinks subreddit that discusses this very topic in much greater detail

The earlier you lock in the cards you want, the better

Pikachu ex 276 SIR Im not certain, and please let me know if Im wrong, but I think this might be the first time the same Pokmon has had two different SIRs in the same set